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CONFORMATIONS OF CYCLOHEXANE
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Advanced Chemistry
5 Views • Aug 07, 2024
Description
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Cyclohexane, a six-membered ring, can exist in various conformations due to rotation around its carbon-carbon single bonds. The main conformations are:
1. Chair conformation:
- Most stable, with minimal steric hindrance
- All bond angles are approximately 109.5° (tetrahedral)
- Hydrogen atoms are either axial (perpendicular to the ring) or equatorial (in the plane of the ring)
2. Boat conformation:
- Less stable than chair, with some steric hindrance
- Bond angles are distorted from tetrahedral
- Hydrogen atoms are either axial or equatorial
3. Twist boat conformation:
- Intermediate stability between chair and boat
- Bond angles are slightly distorted from tetrahedral
- Hydrogen atoms are either axial or equatorial
4. Half-chair conformation:
- Unstable, with significant steric hindrance
- Bond angles are significantly distorted from tetrahedral
5. Planar conformation:
- Highly unstable, with
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